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A chemical change is a change in which molecular composition of taken reactants changes.

If water decomposes to hydrogen and oxygen then it is a chemical change while freezing or boiling of water is a physical change as it's composition remains same.

Now if we take the case of boiling water with magnesium strips a colorless and odorless gas is evolved which can be collected using suitable arrangements. The colorless gas can be only water vapor or hydrogen( from decomposition of water ) or it can be a mixture of both of them. If we remove the water vapor using desiccating agent from the collected gas and them test the gas for combustion we will find that it is a supporter of combustion. This shows that gas is not water vapor but hydrogen. But hydrogen was not taken initially, hence we conclude that hydrogen was produced due to decomposition of water. Since the composition has changed so it is concluded that a chemical change has occurred.

Here is the chemical equation :

Mg + 2H2O --> Mg(OH)2 + H2

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