Dispersion
Benzene is a tidy, symmetrical molecule and packs very efficiently. The methyl group sticking out in methylbenzene tends to disrupt the closeness of the packing. If the molecules aren't as closely packed, the intermolecular forces don't work as well and so the melting point falls.
The intermolecular forces are hydrogen bonding.
Organic solvents that can dissolve naphthalene include benzene, toluene, xylene, and tetrahydrofuran (THF). These solvents have a non-polar nature and are capable of breaking the intermolecular forces holding naphthalene together.
Neon (Ne) is a noble gas and primarily exhibits weak intermolecular forces known as London dispersion forces, which arise from temporary dipoles formed due to fluctuations in electron distribution. Since Ne is nonpolar and has a complete outer electron shell, it does not engage in dipole-dipole interactions or hydrogen bonding. The strength of the London dispersion forces increases with the size and polarizability of the atom; however, in the case of Ne, these forces remain relatively weak compared to other types of intermolecular forces in larger molecules.
Yes, hexane is soluble in benzene because they are both nonpolar hydrocarbons. Both molecules have similar structure and intermolecular forces, allowing them to mix easily.
Acetone evaporates faster than chloroform and benzene because it has a lower boiling point and higher vapor pressure. This means acetone molecules have more kinetic energy, allowing them to overcome intermolecular forces and escape into the air more readily. Chloroform and benzene have stronger intermolecular forces, requiring more energy to break these bonds and evaporate.
Dispersion
The relative strength of intermolecular forces depends on the types of molecules involved. Compounds with hydrogen bonding, such as water, tend to have stronger intermolecular forces compared to those with only London dispersion forces, like diethyl ether. This results in higher boiling points for compounds with stronger intermolecular forces.
Benzene is a tidy, symmetrical molecule and packs very efficiently. The methyl group sticking out in methylbenzene tends to disrupt the closeness of the packing. If the molecules aren't as closely packed, the intermolecular forces don't work as well and so the melting point falls.
Nonpolar solids with weak intermolecular forces are most soluble in benzene. This is because benzene is a nonpolar solvent, so it tends to dissolve nonpolar substances more readily. Examples of solids that are typically soluble in benzene are nonpolar organic compounds like certain hydrocarbons or aromatic compounds.
The intermolecular forces between two xenon atoms would be London dispersion forces, which are weak forces caused by temporary fluctuations in electron distribution. Xenon, being a noble gas, does not have permanent dipoles or hydrogen bonding that would contribute to other types of intermolecular forces.
Dipole-dipole interactions and van der Waals forces of attraction
Molecules with hydrogen bonding have the strongest intermolecular forces. This includes molecules containing hydrogen bonded to highly electronegative atoms like oxygen, nitrogen, or fluorine. These intermolecular forces are stronger than other types such as dipole-dipole or van der Waals forces.
No, Benzene is a flammable liquid at normal temperature and pressure. It will freeze and become a solid if the temperature falls below its melting point, which is 42 oF (5.5 oC)
Benzene is volatile because it has a relatively low boiling point (80.1°C) compared to other compounds. This means it easily evaporates at room temperature, leading to its high volatility. Additionally, benzene has a nonpolar structure, which allows its molecules to experience weak intermolecular forces and escape into the gas phase more easily.
Intramolecular forces are not intermolecular forces !