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A white dwarf star starts out like a our sun and turns into a white dwarf at the end of the stars life cycle. They have used up all their nuclear energy. At the end of this nuclear burning stage the star expels most to all of its outer materials. This creates what is known as a planetary nebula. The hot core is the only part of the star that remains. Temperatures of the core can and will exceed 100,000 Celsius becoming a very hot white. From this point the star starts to cool down, but that takes a billion years or more.

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