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As with many inventions there is no simple answer.

The electric cell was invented not discovered.

The Daniel cell (1836) is possibly the first example of electric cells, these were an improvement on the Leyden jars (1745), independently invented by Kliest and Musschenbroek. These were more like what we would refer to as capacitors.

Volta then improved these further to what we would recognised today as a battery. That is, several 'cells' connected together which he referred to as a 'Crown of Cups'.

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