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1-butanol is soluble in water up to 7.4 %wt at 20oC and 7.7 %wt at 30oC, in other words if you add in less than this percentage it will dissolve. Beyond it, the water will start rejecting the 1-butanol and the solution will turn cloudy or more appropriate wording, turbid and will separate if left to settle. This happens because of the hydrophobic nature of the hydrocarbon chain will become stronger than the hydrophilic -OH group, so the larger the chain the less that will dissolve as with 1-pentanol where the solubility is 2 %wt at 20oC.

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