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Why does physisorption decrease with the increase of temperature?
Physisorption is weaker than chemisorption and is typically dependent on van der Waals forces. As temperature increases, the thermal energy disrupts these weak interactions between the adsorbate and the surface, leading to a decrease in physisorption.
Is ionisation enthalpy of potassium higher than that of sodium?
The ionisation enthalpy of potassium is lower than that of sodium.
How do you know if an enthalpy change diagram is endothermic or exothermic?
If you plot the reaction coordinate (what I think you mean by "enthalpy change diagram"), the reaction will be exothermic if the products are lower on the graph than the reactants. If they are higher than it is endothermic. For instance, if you go to the linked Wikipedia page (link to the left of this answer), the graph shown is of an exothermic reaction.
What is a negative enthalpy?
Negative enthalpy refers to a situation in which a process or reaction releases energy, typically in the form of heat, to its surroundings. This indicates that the enthalpy change (ΔH) for the reaction is less than zero, signifying an exothermic process. In practical terms, reactions with negative enthalpy contribute to an increase in the temperature of their environment, often making them spontaneous under certain conditions.
Why does surgical spirit evaporate faster than water?
The ethanol enthalpy of vaporization is lower compared to water.
Why does physisorption decrease with the increase of temperature?
Physisorption is weaker than chemisorption and is typically dependent on van der Waals forces. As temperature increases, the thermal energy disrupts these weak interactions between the adsorbate and the surface, leading to a decrease in physisorption.
Is ionisation enthalpy of potassium higher than that of sodium?
The ionisation enthalpy of potassium is lower than that of sodium.
How do you know if an enthalpy change diagram is endothermic or exothermic?
If you plot the reaction coordinate (what I think you mean by "enthalpy change diagram"), the reaction will be exothermic if the products are lower on the graph than the reactants. If they are higher than it is endothermic. For instance, if you go to the linked Wikipedia page (link to the left of this answer), the graph shown is of an exothermic reaction.
What is the difference between the bond enthalpy of the reactants and the bond enthalpy of the products in a chemical reaction?
The difference between the bond enthalpy of the reactants and the bond enthalpy of the products in a chemical reaction represents the energy change that occurs during the reaction. If the bond enthalpy of the products is lower than that of the reactants, it indicates that energy is released during the reaction, making it exothermic. Conversely, if the bond enthalpy of the products is higher than that of the reactants, it indicates that energy is absorbed during the reaction, making it endothermic.
Why is enthalpy change of atomization of bromine is higher than bond enthalpy?
The enthalpy change of atomization of bromine is higher than its bond enthalpy because it accounts for breaking the diatomic molecule into individual bromine atoms in the gas phase, which requires overcoming intermolecular forces. Bond enthalpy, on the other hand, only considers the energy needed to break the specific bond in a molecule, not breaking the entire molecule into individual atoms.
What is the definition of physisorption?
Physisorption is the reversible adsorption of molecules onto a surface due to weak van der Waals forces. It involves physical interactions rather than chemical bonds, and can occur in processes such as gas adsorption on solid surfaces.
In an exothermic reaction is the energy of the products higher or lower than that of the reactants?
In an exothermic reaction the energy of the products is less than that of the reactants.
How does molar enthalpy of fussion of ice compare with the molar enthalpy of fussion of other solids?
The molar enthalpy of fusion of ice is relatively high compared to the molar enthalpy of fusion of many other solids. This is because ice requires a significant amount of energy to change from a solid to a liquid state due to its strong hydrogen bonds. However, there are some solids, such as metals, that have higher molar enthalpies of fusion than ice.
How do you know if a reaction is entropy driven enthalpy driven or driven by both enthalpy and energy?
If the ∆H is positive and the ∆S is positive, then the reaction is entropy driven. If the ∆H is negative and the ∆S is negative, then the reaction is enthalpy driven. If ∆H is positive and ∆S is negative, then the reaction is driven by neither of these. If ∆H is negative and ∆S is positive, then the reaction is driven by both of these.
What is the sign of the enthalpy change for an endothermic reaction?
Endothermic reaction: In an endothermic reaction, the products are higher in energy than the reactants. Therefore, the change in enthalpy is positive, and heat is absorbed from the surroundings by the reaction therefore enthalpy change show positive sign in a endothermic reaction..
Which enthalpy is higher 2 Cl or cl2?
The enthalpy of Cl2 (chlorine gas) is higher than 2 Cl (two atoms of chlorine). This is because forming Cl2 from two Cl atoms involves the breaking of an existing bond between the atoms, which requires energy input, whereas 2 Cl atoms do not require this bond formation energy.
How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium?
Sodium has only one valence electron, and when that is donated to some other atom, the remaining ion has a noble gas configuration that is highly stable. Disrupting that by another ionization requires much energy. Magnesium has two valence electrons; therefore the second is almost as easy to donate as the first. The third ionization enthalpy of magnesium would be very high.
