Atomic absorption spectroscopy is the use of principles of atomic absorption of light to determine how much of a metallic element is in a sample. It works by using a few principles which are faily simple and easy to understand on their own and are then combined to make the machine and cause it to work. Let's have a quick look. When we burn something, we can, if we burn it hot enough, break it down into atoms. As metal atoms are burned, we're going to excite them. That is, we're going to excite their outermost electrons and push them to higher energy levels. Note that there are a couple of quantum mechanical rules that an electron must follow. First, it will only jump to a specific higher energy level. A higher level always exists, but what that means is that there are no "half-levels" or "sorta close" situations. And the jump represents a specific quantity of energy. Also, that electron must get exactly the right quantity (get it? quantity? quantum?) of energy in a packet to make the jump. That means that if it doesn't get enough, it doesn't make a "half-jump" and if it gets too much, it will reject the packet of energy. The transition will only occur with the absorption of the exact quantity of energy needed to make that specific transition. Good? Let's jump. We burn our sample in a flame or furnace. Then we shine a special light through it. This special light is for a specific metal. It emits photons of just the right energy necessary for the valence electrons to make that jump to the next energy level. (That's the "level thingie" we just talked about.) It's a setup, 'cause we picked our light source to have just the right energy of light for this metal. So with the light shining and the sample burning, we look at the light coming out the other side of the flame. There won't be as much light coming out as went in, because some of the valence electrons in our sample absorbed some of the light and moved out to the next energy level for a moment. The more atoms of that metal we're looking for that are in our sample, the more light photons there are that "won't make it" through the flame. They got absorbed by valence electrons. With it so far? Good. One more thing and we're good. We can look at the amount of light coming through the flame before we burn our sample to "calibrate" the unit. Then we burn our sample and look at the amount of light coming through the flame. The more light that doesn't make it, the more that had to have been absorbed by the metal (specifically its valence electrons) in our sample. And that would mean that there was "more" of the metal in our sample. We can actually quantify (tell how much) metal was in our sample by this method, which we call atomic absorption spectroscopy. You got a couple of links if you want them. At least look at the drawing and the cool pics in the first link. It should lock things in for ya.
Atomic absorption lines are very narrow because they result from the absorption of light by individual atoms at specific energy levels. This absorption occurs at precise wavelengths corresponding to the energy differences between the atom's electron orbits. The narrowness of the lines is due to the limited number of possible energy transitions within an atom, resulting in distinct and well-defined absorption peaks.
According to modern atomic theory, electrons can move from one energy level to another within an atom. This movement between energy levels is responsible for the emission or absorption of electromagnetic radiation in the form of photons.
Energy transfer on the atomic level occurs through interactions such as collisions between atoms or through electromagnetic forces like radiation. When atoms collide, kinetic energy is transferred from one atom to another. Electromagnetic forces can transfer energy through the emission or absorption of photons by atoms.
The rate of absorption and radiation depends on factors such as the material involved, its density, thickness, and the wavelength of the radiation. For absorption, the nature of the material in terms of its atomic structure and energy levels also plays a significant role. Similarly, the radiation rate is affected by the temperature of the material and whether any external sources are providing energy.
Absorption in physics refers to the process by which matter takes in energy or particles from its surroundings. This can occur in various forms, such as the absorption of light by a material, the absorption of sound waves by a medium, or the absorption of energy by an electron transitioning to a higher energy level.
Atomic absorption lines are very narrow because they result from the absorption of light by individual atoms at specific energy levels. This absorption occurs at precise wavelengths corresponding to the energy differences between the atom's electron orbits. The narrowness of the lines is due to the limited number of possible energy transitions within an atom, resulting in distinct and well-defined absorption peaks.
Atomic absorption is more sensitive to atomic emission when the excitation potential is greater than 3.5eV.
Atomic absorption spectrometry is more sensitive than atomic emission spectrometry.
The absorption spectrum of boron typically shows strong absorption in the ultraviolet region, with some absorption in the visible spectrum as well. Boron's absorption spectrum is characterized by a series of sharp peaks due to transitions between energy levels in its atomic structure.
Atomic absorption spectrometry is used for the determination of metal residues remaining from pharmaceutical manufacturing.
Atomic absorption spectroscopy is used by chemists, environmental scientists, and researchers to detect and quantify the concentration of metallic elements in a sample. Industries such as pharmaceuticals, agriculture, and metallurgy also rely on atomic absorption spectroscopy for quality control and regulatory compliance.
According to modern atomic theory, electrons can move from one energy level to another within an atom. This movement between energy levels is responsible for the emission or absorption of electromagnetic radiation in the form of photons.
William John Price has written: 'Spectrochemical analysis by atomic absorption' -- subject(s): Atomic absorption spectroscopy
Ted Hadeishi has written: 'Zeeman atomic absorption spectrometry' -- subject(s): Atomic absorption spectroscopy, Zeeman effect
Atomic absorption spectrometry is the measurement of the absorption of optical radiation by atoms in the gaseous state. Usually only absorptions involving the ground state, known as resonance lines, are observed.
Atomic absorption is used in forensics to analyze trace elements in samples such as blood, hair, or soil. By measuring the absorption of specific wavelengths of light by the atoms in the sample, atomic absorption spectroscopy can determine the presence and concentration of elements like arsenic, lead, or mercury, which can be crucial in solving criminal cases.
Energy transfer on the atomic level occurs through interactions such as collisions between atoms or through electromagnetic forces like radiation. When atoms collide, kinetic energy is transferred from one atom to another. Electromagnetic forces can transfer energy through the emission or absorption of photons by atoms.