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I'm guessing you are analyzing an experiment where you are determining the molecular mass of an organic liquid. You heated the flask and the liquid evaporated filling the flask, but escaping through a small hole in the covering.

1. Gases always fill the container. So, if the liquid evaporated and formed a gas (vapor), it filled the flask,

2. The pressure on the outside the flask is air pressure. since the vapor isn't pushing off the cover, the pressure is not higher than the air pressure. But since the extra escaped, it cannot be less than the air pressure. Therefore, it is the same.

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Q: When all the liquid has evaporated the vapor totally fills the florence flask and exerts a pressure equal to the atmospheric pressure why?
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