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It only happens on limestone and gypsum, and the result is karst landscape including limestonepavement andcaves.

Rain water is naturally acid from absorbed atmospheric carbon dioxide, and the calcium carbonate is precipitated as that from the solution. E.g. kettle scale.

Acidity from sulphur dioxide will hasten the process very, very slightly - and produce gypsum (calcium sulphate). This is exploited in flue-gas de-sulphurisers fitted to coal-burning power-stations. Gypsum is harmless - it does occur as a rock - butis also the main ingredient of plaster.

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