It depends on which website you're using. There is no chat option on Answers, but you can send a message by going to a user's profile and clicking on the envelope icon at the top of their profile page.
If you're using Facebook:
Click on the magnifying glass in the lower right-hand corner of your screen. Click on "Options," and choose "Turn On Chat." Then type in the user's name you want to start a chat with.
If you're using Google:
Click on "Search" and find the person you want to start a chat with. By clicking on their name, you can start a chat. By typing in their email address, you can invite them to chat.
Penguin Chat started out in 2000
omegle does not allow this. For random live chat iddin is also good.
Once you installed it, in the chat area, by your name, you should have a green camera. If your friends have the same sign then start chatting with them. In the chat it will have a tab that says video and more, press on start video chat or start voice chat. You then talk to each other by webcam.
A new private chat room can be created from the XMB (while not in a game) by first selecting Friends List and there should be an option for Start New Chat. From there, selecting Voice chat will create a new private chat room.
You have to choose a different chat when you first start the game. Sorry
I START IT IN A CHAT ROOM
The chat box in Gmail pops up as soon as you start a chat. The chat can be started by clicking on any contact. The box appears on bottom right.
ok you can to find very good rooms online on these sites: anamiros.com, icq, facebookA chat channel in Online Chat is a way to start online chat. People usually start online chat with two different tools, one-to-one or one-to-many. One-to-one chat tools are used for personal communication, such as ICQ, Skype, MSN, etc.
Its easy-)
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go up to them and start talking to them