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You should not paint a thermocouple.
You can paint on a photograph. Normal acrylic would work.
I went to buy new hubcaps for my car.
Preferably paint that has not already dried solid inside the paint can. I would highly recommend this type for most any use on an interior or exterior surface.
Acrylic wall paint you can buy at lowes or home depot.
You can paint your car blinkers with spray paint. You can use any type of Marine spray paint. The spray paint should be water resistant.
Oil Based
A good oil based primer, then an oil based concrete paint.
I would use a spray enamel. Should be enough in 1 can.
If indoors use emulsion Matt or silk depending on what finish you want.
Any interior paint should work; if you use a roller, a bit of texture will be added naturally.
You can paint the exterior of your above ground pool. You will first have to clean it and use sand paper to lightly scruff the surface. You should use an exterior primer to prime the surface, and then an exterior paint designed for the type of surface your are painting to paint it.