The equation is as follows:
CH2OH(CHOH)4CHO(aq) + 2Ag(NH3)2+(aq) + 3OH- (aq) →
(Glucose) (Tollen's Reagent, Ammoniacal Silver Nitrate)
2Ag(s) + CH2OH(CHOH)4COO-(aq) + 4NH3(aq) + 2H2O(l)
(Silver metal, (Gluconic acid)
which forms silver mirror)
Does not react. Because Tollens' reagent only works with aldehydes. Butanone is methyl ethyl ketone (MEK).
Glucose oxidizes very quickly, and creates a silver mirror layer between the glucose solution and the Tollens' reagent. This is because of how the ketose reacts and reduces the silver molecules in Tollen's reagent.
no negative
No, the Tollen's Silver Mirror Test only confirms the presence of aldehydes.
All the compounds having free aldehyde group as reducing sugars.
ch61206
Does not react. Because Tollens' reagent only works with aldehydes. Butanone is methyl ethyl ketone (MEK).
wrt
2[Ag(NH3)2]+ + CH3CHO + 3OH- --> 2Ag + 2H2O + 4NH3 + CH3COO-
Bernhard Tollens was born on 1841-07-30.
Bernhard Tollens died on 1918-01-31.
Hendrik Tollens died on 1856-10-21.
Hendrik Tollens was born on 1780-09-24.
Mudus Tollens = "the way that denies by denying"
Tollens are chemical reagents that are commonly used to determine whether a known carbonyl containing compound is an aldehyde. It is stated that CH3CHO will not react to tollens at all.
Tollens' reagent is used to determine whether a carbonyl containing compound is an aldehyde or a ketone. Acetone is a ketone so it will not readily react with Tollens' reagent.
When adding the aldehyde or ketone to Tollens' reagent, the test tube is put in a warm water bath. If the reactant under test is an aldehyde, Tollens' test results in a silver mirror. If the reactant is a ketone, it will not react because a ketone cannot be oxidized easily. A ketone has no available hydrogen atom on the carbonyl carbon that can be oxidized - unlike an aldehyde, which has this hydrogen atom.