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Because unlike the empirical formula, the molecular formula does not have to be the simplest ratio.

If by chance you are given the percent composition of the elements in a substance, you could calculate the empirical formula and then the empirical formula's mass. However, the molecular formula equation is molecular formula= (empirical formula)n, where n is the mass of the molecular formula divided by the mass of the empirical formula. You would, therefore, need to know the mass belonging to the molecular formula, which you are not given.

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Q: Explain why the percent composition of certain compounds are not sufficient to determine the compounds molecular formulas?
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