Simply put, boiling is the process by which a liquid becomes a gas while condensation is the opposite; it is the process by which a gas becomes a liquid.
Distillation
If you have a liquid which is a mixture of different chemicals which have different boiling points, you can boil them off, one chemical at a time, capturing the resulting vapor and condensing it into a pure chemical.
Boiling a fermented liquid and then condensing and capturing the alcohol as it cools.
A still consists of a boiling chamber connected to copper tubing at the top. The tubing runs into a condensing chamber. The boiling chamber should be sealed s so that the only way out for the steam is through the condensing tube.
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Temperature glide
If it is melting, boiling, condensing, subliming, or depositing, then it is changing state.
This is known as a distillation. Ethanol and water can be separated using this process because their boiling points are different which allows them to be "boiled off" at different temperatures.
We can separate a mixture of different liquids in the process of distillation by evaporating and condensing to make sure nothing is dissolved in it. Distillation as a separation method is based on the differences between boiling points of liquids.
Crude oil can be separated using fractional distillation because its different components have different boiling points. By heating the crude oil and allowing it to vaporize, then condensing the vapor at different temperatures, the various fractions (like gasoline, diesel, and kerosene) can be collected separately based on their boiling points.
Yes, changes of state (melting, boiling, freezing, condensing) are physical processes.
Freezing (melting, boiling, condensing) are always phycal changes (of matter)