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The Negative - Battery Cable will be connected to ground. Ground is the engine block, frame, or other non-electrical part of the vehicle. The other cable is positive. Another way is to connect an ohm meter black test probe to the engine block and touch the red test probe to the cable you think is ground -. If the circuit is complete you have found the negative cable.

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Q: How do i identify negative and positive battery cables on a 1991 ford mustang. there are no red or black markings?
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