I don't have specific knowledge on this vehicle. But typically, an engine numbers the cyclinders either clock wise or counter-clock wise looking down on the engine block.
You can then Google the firing order of your vechicle and match that to the order in which the sparkplug wires are ordered on the coil.
After this, you should have some idea on the cylinder 3 location.
The 2014 Toyota Avalon has a V6 engine.
The 2012 Toyota Avalon has a V6 engine.
The 2005 Toyota Avalon has a V6 engine.
The 2008 Toyota Avalon has a V6 engine.
The 2003 Toyota Avalon has a V6 engine.
The 2009 Toyota Avalon has a V6 engine.
The 2004 Toyota Avalon has a V6 engine.
The 2001 Toyota Avalon has a V6 engine.
The 2013 Toyota Avalon has a V6 engine.
The 2010 Toyota Avalon has a V6 engine.
The 2011 Toyota Avalon has a V6 engine.
The 2006 Toyota Avalon has a V6 engine.