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For a partly ionically bonded compound such as calcium carbonate, the gram formula mass is substituted for a mole, which technically exists only for purely covalently bonded compounds. The gram formula mass for calcium carbonate is 100.09. Therefore, 200 grams constitutes 200/100.09 or 2.00 gram formula masses of calcium carbonate, to the justified number of significant digits.

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Q: How many moles are there in 200 grams of Calcium Carbonate?
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