You're talking apples and Oranges. In point of fact, both of these things are sin, but of a different variety. Catholics are against divorce because a true sacramental marriage between a man and a woman lasts until death and there is nothing that anyone can do to separate them, a civil divorce may be allowed in certain extreme cases (abuse, etc.) but there is no actual divorce, they remain married, just living apart under a civil divorce.
"Gay marriage" is an entirely different thing. It is rooted in the sin of sodomy which is actually sacrilege, the sin of sodomy is one of the four in The Bible of the "sins that cry to heaven for venegance" (along with murder, oppression of the poor and defrauding workers of their due wages).
59% of Alabama residents oppose same-sex marriage as of 2015.
35% of Alaska residents oppose same-sex marriage as of 2015.
48% of Louisiana residents oppose same-sex marriage as of 2015.
48% of Oklahoma residents oppose same-sex marriage as of 2015.
The National Organization for Marriage, the Roman Catholic Church and the Republican Party all oppose same-sex marriage.
Oppose. She says she fears gay marriage will make god angry.
59% of Arkansas residents oppose same-sex marriage as of 2015.
47% of Georgia (US) residents oppose same-sex marriage as of 2015.
49% of Kansas residents oppose same-sex marriage as of 2014.
55 percent of Tennessee residents oppose same-sex marriage as of 2015.
41% of Idaho residents oppose same-sex marriage as of 2015.
They oppose it.