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Pineau des Charentes is made from lightly pressed Grape Juice and one-year-old cognac eau-de-vie (which is the distillate of the same grape juice). The two are assembled when the fresh grape juice has undergone a few days to a few weeks of fermentation, although some assembly is almost immediate.
The eau-de-vie is chosen for its flavour, strength and body, and also for its alcohol content. The science face of making a pineau is ensuring the sugar content of the grape juice and alcohol content of the eau-de-vie will combine to build a pineau that is within regulations.
There are no other flavours added, as if a pineau is changed in any way, shape or form it can no longer be labeled a pineau.
Therefore, the answer is no.
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