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pH = 4 is about in the middle (4.7) of the values pH=pKa,1 and pH=pKa,2.

This is an indication of H2PO4- abundantly being present, because

  1. at pH=2.14 it is halfway forming its conjugate acid H3PO4

    and

  2. at pH=7.21 it is halfway forming its conjugate base HPO42-
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13y ago
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2w ago

At pH 4, the predominant form of phosphoric acid would be H2PO4-, as it is the species that corresponds to the second pKa. This is because when the pH is between the first and second pKa values, the acid primarily exists in its second protonated form.

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Q: Phosphoric acid H3PO4 has three dissociable protons with pkas 2.14 and 6.86 and 12.4 which form of the acid predominates in a solution of pH 4?
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Phosphoric acid has three dissociable protons, making it triprotic. Therefore, its basicity is 3.


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The basicity of phosphoric acid is?

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Why is phosphoric acid called a triprotic acid?

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