left, right, or center
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It is on the Alignment tab.
Ctrl - 1 - A will open the Alignment Tab in the Format Cells dialog box.
The "Alignment" tab
Highlight all the cells across the columns where you want to center the text.Select cell format and choose alignment, then check merge cells.Observe that now you have one cell that combines all the highlighted cells.Type your text and select center.
The main ones are left, right, center and justify. Go to the Format Cells dialog box, by pressing Ctrl - 1 and you can get to the Alignment settings from there.
Press Ctrl - 1 to open the Format Cells dialog box. Go to Alignment and in there you will find the orientation setting. You can use it to change the angle of the text.
Press Ctrl - 1 to go to the Format Cells dialog box. Then pick the Alignment tab. In Text Alignment section, set the Vertical Alignment to Center.
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Horizontal alignment is the positioning of content in the cell across, like to the left, right or centre. Vertical alignment is the position of the content from the top of the cell to the bottom of a cell. If a cell is increased in height over its usual setting, then the vertical alignment can be used to position content at the top, middle or bottom of a cell. Both vertical and horizontal alignment can be done on the Alignment tab in the Format Cells dialog box. Pressing Ctrl-1 will open it.
Format chart area
Rotating Text