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Pressure is not affected by enthalpy and entropy.
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When graphing enthalpy and entropy what variables are included?

Temperature and energy are two of the variables included when graphing enthalpy and entropy. Enthalpy is made up of the energy, pressure, and volume of a system. Entropy is a way to determine the different ways energy can be arranged.


Is Delta S is the change in enthalpy a measure of randomness?

No, ΔS (change in entropy) and ΔH (change in enthalpy) are not measurements of randomness. Entropy is a measure of the disorder or randomness in a system, while enthalpy is a measure of the heat energy of a system. The change in entropy and enthalpy can be related in chemical reactions to determine the overall spontaneity of the process.


How do you calculate melting points and boiling points by using enthalpy and entropy?

The melting point and boiling point of a substance are related to its enthalpy of fusion and vaporization, respectively, and its entropy of fusion and vaporization. The melting point is where the solid and liquid phases are in equilibrium, while the boiling point is where the liquid and vapor phases are in equilibrium. By analyzing the balance between enthalpy and entropy changes during phase transitions, you can predict and calculate melting and boiling points.


What is the melting point equation for a substance?

The melting point equation for a substance is typically represented as Hfusion TmSfusion, where Hfusion is the enthalpy of fusion, Tm is the melting point temperature, and Sfusion is the entropy of fusion.


What is the definition of enthalpy and entropy?

Enthalpy is the amount of energy released or used when kept at a constant pressure. Entropy refers to the unavailable energy within a system, which is also a measure of the problems within the system.


What aspect of a substance contributes to a high or low entropy?

The complexity or disorder of a substance contributes to its entropy. A substance with more possible arrangements of its particles has higher entropy, while a substance with limited arrangements has lower entropy.


What could make delta G become negative at a given enthalpy and entropy?

For delta G to become negative at a given enthalpy and entropy, the process must be spontaneous. This can happen when the increase in entropy is large enough to overcome the positive enthalpy, leading to a negative overall Gibbs free energy. This typically occurs at higher temperatures where entropy effects dominate.


What is the relationship between enthalpy, entropy, and free energy in a chemical reaction?

In a chemical reaction, enthalpy, entropy, and free energy are related. Enthalpy is the heat energy exchanged during a reaction, entropy is the measure of disorder or randomness, and free energy is the energy available to do work. The relationship between these three factors is described by the Gibbs free energy equation: G H - TS, where G is the change in free energy, H is the change in enthalpy, S is the change in entropy, and T is the temperature in Kelvin. This equation shows that for a reaction to be spontaneous, the change in free energy must be negative, meaning that the enthalpy change and entropy change must work together in the right direction.


How do you know if a reaction is entropy driven enthalpy driven or driven by both enthalpy and energy?

If the ∆H is positive and the ∆S is positive, then the reaction is entropy driven. If the ∆H is negative and the ∆S is negative, then the reaction is enthalpy driven. If ∆H is positive and ∆S is negative, then the reaction is driven by neither of these. If ∆H is negative and ∆S is positive, then the reaction is driven by both of these.


What could make G become negative at a given enthalpy and entropy?

Changing the temperature


How does gibbs energy relate to the changes in ethalpy and ethropy?

Gibbs energy accounts for both enthalpy (heat) and entropy (disorder) in a system. A reaction will be spontaneous if the Gibbs energy change is negative, which occurs when enthalpy is negative (exothermic) and/or entropy is positive (increased disorder). The relationship between Gibbs energy, enthalpy, and entropy is described by the equation ΔG = ΔH - TΔS, where T is temperature in Kelvin.


What is the relationship between the enthalpy h and entropy s of a reaction that is spontaneous at higher temperatures but not at lower temperatures?

The relationship between enthalpy (H) and entropy (S) is described by the Gibbs free energy equation, ΔG = ΔH - TΔS, where ΔG is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy. For a reaction to be spontaneous at higher temperatures but not at lower temperatures, the entropy term (TΔS) must dominate over the enthalpy term (ΔH) in the Gibbs free energy equation. This suggests that the increase in entropy with temperature plays a more significant role in driving the reaction towards spontaneity than the enthalpy change.