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In the same volume of water, one mole of MgCl2 will give rise to a greater boiling point elevation. This is explained by the fact that boiling point elevation is a colligative property, that is, the relative amounts of the constituents are important and not their identity.

We can determine by inspection that, upon dissociation, more ions will be produced by MgCl2 than NaCl since there are more atoms in the MgCl2 molecule. So, for one mole of MgCl2, we will produce one mole of magnesium and two of chlorine (three total). For one mole of NaCl, we produce one mole each of potassium and chlorine. By employing the principle stated above, we can come to the correct conclusion.

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Q: What has a greater boiling point elevation when dissolved at a concentration of 1mol in water with NaCl or MgCl2?
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