From Wikipedia: POP3 access is now available for all Hotmail accounts in United States, United Kingdom, Canada, Brazil, Australia, France, Japan, Spain, Germany, Italy, and the Netherlands as of February 2009. [27] Countries that do not have POP3 access enabled for free, Hotmail plus costs $19.95 for each year the user is subscribed to the service, and POP3 access is available to all other countries through that service.[28] Alternatively, users can change their country in Hotmail options to a country that has enabled free POP3 access. It should work automatically.
Hotmail does not support pop3 unless you are a paying subscriber. GMX.com is free mail that does support pop3 and imap.
Hotmail's incoming mail server for POP3 is pop3.live.com on port 995. Hotmail's incoming mail server for IMAPis imap-mail.live.com on port 993.
You can transform your hotmail account into a POP3 account via Izymail (izymail.com). Either you can let Izymail forward your hotmail emails into your Gmail inbox, or you can use Gmail to automatically download your hotmail emails.
pop3.email.msn.com
pop3.live.com
Call technical support for instant solution for all Hotmail Account and Pop3 issues 1-866-503-0571
Hotmail Now Offers POP3! http://mailcall.spaces.live.com/blog/cns!CC9301187A51FE33!49799.entry
Pop3 provides facilities to users to access mailboxes and download messages to their computers. Pop3 allow the clients to retrieve mail via TCP or IP address, it does not send mail. This can be very beneficial to mobile devices that have no permanent network connection by holding their mail in their Pop3 mailbox until they can retrieve it.
You can use the Email app (not GMail) bundled as standard with the Android device to access Hotmail. To do this you may need the Hotmail POP3 settings.
Hotmail Incoming Mail Server (POP3) - pop3.live.com (logon using Secure Password Authentification - SPA, mail server port: 995) Hotmail Outgoing Mail Server (SMTP) - smtp.live.com (TLS enabled, port 587), these settings should do the trick for your incoming and outgoing mail needs.
There is a possibility that Outlook does not support Pop3 mail types, like hotmail and yahoo.
From the current looks of it, it won't. According to the support team, the current Hotmail system wasn't built to support IMAP. However, Hotmail was late to support POP3, so it could be possible that they'll be slow to support IMAP as well.