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Vaccuum canister, to remove fuel vapors from the gas tank.

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Q: What is the black cylinder next to the overflow tank in a 96 Mercury grand Marquias?
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What does it mean when the overflow tank is bubbling and the car overheat?

If the tank bubbles all the time the engine is running and is black dirty inside the head gasket has failed or a similar failure like a cracked cylinder head. If it only bubbling after the engine is overheated, the system needs to be checked for other failures.