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A superelastic collision is when the total kinetic energy AFTER a collision is more than the total kinetic energy BEFORE the collision.
It's more easily seen when examining the speeds (the masses will normally stay the same) of the two objects. When the speeds are faster AFTER the collision than BEFORE the collision, you likely have a superelastic collision. (Kinetic Energy equals 1/2xMassxSpeed^2) When the speed increases there is a larger kinetic energy.
Before you implode (I almost did) from the disregard of the first law of thermodynamics (that energy can't be created or destroyed, only transferred and transformed), the increase in kinetic energy is most likely a conversion of potential energy to kinetic energy.
An example would be two carts with springs colliding and creating a supercollision. Since the springs are triggered because of the collision, their potential energy will be converted into kinetic energy and the carts will leave the collision with a larger velocity and thus more kinetic energy.
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