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We have 495 ml, but we need to convert this to 1000, so we divide by 495 and multiply by 1000. We also do this to 21.1g. 21.1/495*100 is 42.626g. KI's molecular weight is 166g/mol. 42.626/166 is 0.2568 molar.

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Q: What is the molarity of 495 mL solution containing 21.1 g of potassium iodide?
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