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Without stating the temperature, this cannot be exactly accurate as density of water fluctuates with temperature. However, it is a fair assumption to use the approximation of 1 kilogram is 1 litre. Therefore you have 6 litres. 3 moles / 6 is 0.5 moles per litre (molar).

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Q: What is the molarity of a solution made by dissolving 3 mol of naoh in 6 kg of water?
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