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The type of metal is not as important as the heat loss characteristics of the head and block casting--airflow, etc. Aluminum or lighter alloys are chosen for the head, which has the most heat to lose; and each has their weaker and stronger points.

A head that is the most efficient at heat loss also expands and shrinks the most; so there are trade-offs. For this reason and others, the block is usually a denser material, but successful all-aluminum, and even a carbon fiber motors (both with steel or other inserts at necessary places) have been built.

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Q: What metal are air cooled engines made from?
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