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You can use shortening, butter or margarine, or even mayonnaise or lard in some recipes. Actually, many chocolate cake recipes call for mayonnaise instead of oil or butter. Just keep in mind that margarine has a higher water content than butter, so you may want to use all butter or half butter/half margarine if that's the substitution you choose.

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Q: What should you use to bake a chocolate cake if you do not have vegetable oil or olive oil?
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