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There is no direct relationship between grams of oxygenand atoms of oxygen. Use the atomic mass to convert grams to moles and Avogadro's number to convert moles to atoms.

Since you are converting from grams O, this goes in the denominator (on the bottom) of the first factor. You want to end up in units of atoms of O, so this goes in the numerator (on the top) of the last factor.

g O1.00 mole O6.02E+23 atom O= atoms O16.0 gram O1.00 mole O

Note that the units grams oxygen "cancel out" in the first factor and you are left in units of moles. Moles cancel out in the second factor and the final units are atoms oxygen.

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Q: What would you multiply grams of oxygen by to get the units atoms of oxygen?
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