sodium metal is deposited at the cathode.
Sodium is obtained at the cathode.
Electrolysis of molten sodium chloride: the products are sodium and chlorine. Electrolysis of sodium chloride solution: the products are hydrogen and chlorine.
In MOLTEN zinc chloride, At the cathode: Zn2+ + 2e- --> Zn(s) At the anode: 2Cl- --> Cl2(g) + 2e- In CONCENTRATED aqueous zinc chloride solution, At the cathode: 2H+ + 2e- --> H2(g) At the anode: 2Cl- --> Cl2(g) + 2e- (Zinc is not formed as it's Enaught value is very negative. Chlorine is still formed though.) In dilute (less than 5%) squeous zinc chloride solution, At the cathode: 2H+ + 2e- --> H2(g) At the anode: 2O2- --> O2(g) + 4e-
When a mixture of 42% NaCl and 58% CaCl2 is electrolysed in Down'cell pure molten sodium metal is obtained.
Sodium metal at the cathode, chlorine gas at the anode
Sodium is deposited at the cathode and chloride gas is evolved at the anode when electricity is passed through molten sodium chloride.
In molten sodium chloride the free moving particles are Na+ and Cl- ions, during electrolysis sodium ion moves towards cathode and chloride ion towards anode.
Electrolysis of molten sodium chloride: yield sodium and chlorine.Electrolysis of sodium chloride water solution: yield hydrogen, sodium hydroxide and chlorine.
Sodium and chlorine are obtained.
In solid state, Aluminium and oxide ions are immobile. When aluminum oxide is melt down,aluminum and oxide ions become free and they can easily migrate to respecve electrodes. Therefore, aluminum oxide is electrolysed in molten state.
Molten sodium chloride: sodium and chlorine. Aqeous solution of NaCl: sodium hydroxide and hydrogen.
When an aqueous solution of sodium hydroxide is electrolyzed, hydrogen is produced at the cathode because hydrogen can be produced at a lower voltage than can sodium, and the supply of hydrogen from the water of the solution is sufficient to consume all the current supplied. When molten sodium chloride is electrolyzed, however, sodium is produced at the cathode.