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It's related to intermolecular forces. HF forms strong H-bonds, therefore, they do not 'steal' or give away electrons, they are held together instead. They hold firmly together even in solution due H-bonds (hence, HF is a weak electrolyte).

For further understaning: http://www.chemguide.co.uk/atoms/bonding/hbond.html

All the above is true however molecules which could only be ionic by forming the H+ ion cannot do it- the H+ ion is a "naked" proton it will always attach to something. HCl is molecular, HBr is molecular they do NOT have hydrogen bonds and yet they are still molecular.

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Q: Why HF is polar covalent not an ionic compound although difference of electronegativities is 1.9?
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