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The cold water reduces the temperature of the glass. The cold glass reduces the temperature of the air around the glass. The amount of moisture in air is temperature dependant hotter air can contain a higher moisture content. If the air temperature is reduced the water condenses. In this case the cold glass reduces the air temperature in contact with the glass, this results in the condenstion of moisture from the air, and water droplets are formed.

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Q: Why do water droplet appear on outer surface of glass when cold water is poured in it?
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