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I am not an expert on this topic, but silicon I believe has access to some D orbitals. Water can exploit this D orbital and bond to the silicone producing an Si-O-H bond and HCl which fumes. I believe this is thermodynamically favorable (si-O-H). Carbon tetrachloride does not have access to D orbitals and can not form the necessary intermediate to react (kinetically hindered). That's my shot at it.

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12y ago
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5d ago

Chloride of silicon reacts with moisture in the air to form hydrochloric acid and silicic acid, producing steamy fumes. Chloride of carbon, on the other hand, does not readily react with air or moisture to release fumes.

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Q: Why does a bottle of the chloride of silicon produces steamy fumes when left open on the bench but a bottle of the chloride of carbon does not?
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