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It sounds like mildew to me. If the freezer is in use, and the black soot is in the interior of the freezer, it's likely something else. But especially if it's in the crevices of the door lining, or if the freezer is not in use, it's likely mildew. Clean it well, wipe it off with a bleach solution, and try to keep it dry. Mildew needs warm, moist, and dark to survive and thrive.

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Q: Why does black soot appear in the freezer compartment of a Kenmore refrigerator?
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