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Because carbonic acid (first pKa about 6.4) is a weaker acid than acetylsalicylic acid (pKa about 3.4) is.

Note that this answer, while technically "correct", is only going to embarrass you in class unless you know enough chemistry to explain it, which probably means you know enough chemistry to have answered it for yourself in the first place. Especially since the question doesn't actually mention carbonic acid; you've got to read between the lines a little to see why that's relevant.

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Q: Why is adding NaHCO3 to the aspirin crystals a chemical change?
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