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Friedel Crafts acylation of naphthalene
To ensure there's enough of it to allow the reaction to go to completion.
The process would be unfavourable since the nitro (-NO2) group is strongly deactivating and would render the benzene ring in nitrobenzene less susceptible to electrophilic attack.
Saturn was discovered by ancient Greeks and Romans, so sorry no space crafts.
non
The nitrogen group is electron withdrawing and therefore deactivates the ring. So, friedel crafts reaction will not take place.
Friedel–Crafts reaction
Friedel Crafts acylation of naphthalene
C. M. Jephcott has written: 'Friedel and Crafts' reaction in the pyridine series'
To ensure there's enough of it to allow the reaction to go to completion.
The name of this reaction is Friedel-Crafts acylation. It should have a major product adding a ketone at the para position with regard to the isopropyl of the cumene.
Jacob Meyer Zeavin has written: 'Preparation of some monoderivatives of benzoic anhydride and their reaction with Friedel-Crafts' synthesis'
Aniline doesnt undergo friedel craft rxn because the reagent AlCl3,(the lewis acid which is used as a catalyst in friedel crafts reaction).being e- deficient acts as lewis base and attacks on the lone pair of nitrogen present in aniline & aniline forms a salt with Aluminium chloride. Due to this nitrogen atom of aniline acquires a positive charge and hence acts as a strong deactivating group and thus doesn 't allow the reaction to take place.In other cases ther is no such reaction.
rearrangemet because primary carbocations cannot form
aluminum chloride
The most important application is to use AlCl3 as catalyst in organic chemistry (as an example for Friedel-Crafts reaction); other applications are: - preparation of aluminium in laboratory - petroleum industry - rubber industry
George A. Olah has written: 'A Life Of Magic Chemistry' 'Friedel-Crafts chemistry' -- subject(s): Friedel-Crafts reaction 'Carbonium ions' -- subject(s): Carbonium ions 'Halonium ions' -- subject(s): Halonium ions 'Superelectrophiles and their chemistry' -- subject(s): Organic compounds, Chemical affinity, Superelectrophiles, Synthesis 'Hypercarbon chemistry' -- subject(s): Organometallic chemistry, Carbonium ions