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If the equilibrium is altered such that the gaseous form is favoured, then the boiling point will be lower as more water molecules will want to evaporate.

One way to do this is to lower pressure. If you decrease the pressure on a container of water, there will be less air pressure at the surface of the solution, and more water molecules will spontaneously have sufficient energy to vaporise into gas. At high altitudes, such as atop the Himalayas, the boiling point of water approaches 90 degrees, 10 degrees lower than at sea level, for this very reason.

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Q: Why will the boiling point of water lower?
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