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There are several titles for the head of the executive branch of a national government, e.g., prime minister, premier and president.
Mayor.
Governor
chief ministerIt depnds on the country.The leader of the government in each of Australia's states is the Premier. "Chief Minister" is the title given to the leader of government in the territories, not the states.
That will depend on the country, as different countries have different titles for the head of the government. Prime Minister is a common title, but there are many others although they have a similar role. It is also possible to have more than one party in a government, so in that case only one of the leaders will be the head of the government and the other leader or leaders will have different titles.