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A cation is an element that loses electrons in order to achieve a pseudo-noble gas electron configuration:

Hence, when a cation loses electrons it has an uneven number of (p+) and (e-). The protons then pull harder on the electrons or (e-) because there is more positive charged subatomic particles than there are negatively charged subatomic particles. The remaining electrons are closer to the nucleus making the cation smaller in size than the original atom.

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