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What is the significance of the standard Gibbs free energy change (G) in chemical reactions?
The standard Gibbs free energy change (G) in chemical reactions indicates whether a reaction is spontaneous (G 0) or non-spontaneous (G 0). It helps determine the direction and feasibility of a reaction under standard conditions.
Is the change in entropy, delta S, positive or negative for a spontaneous reaction?
For a spontaneous reaction, the change in entropy (delta S) is typically positive.
What form a spontaneous reaction at 298 K?
A spontaneous reaction at 298 K is one in which the Gibbs free energy change (ΔG) is negative. This means that the reaction is energetically favorable and will proceed in the forward direction without the need for external energy input.
Is an exothermic reaction always spontaneous?
No, an exothermic reaction is not always spontaneous. The spontaneity of a reaction depends on factors such as temperature, pressure, and the entropy change of the system.
Does all irreversible reactions are spontaneous?
No, not all irreversible reactions are spontaneous - for example, cooking an egg. Once it's cooked, there's no going back to the raw egg stage. But it takes a lot of heat to get to that stage, so it is not spontaneous. If you find an old egg laid by a hen, it will not have a hardboiled texture!
How form a spontaneous reaction 298 k?
A reaction will be spontaneous at 298 K if the Gibbs free energy change (ΔG) for the reaction is negative. This means that the reaction will proceed in the forward direction without requiring an external input of energy. The equation ΔG = ΔH - TΔS can be used to determine if a reaction is spontaneous at a given temperature, where ΔH is the change in enthalpy and ΔS is the change in entropy.
What is the significance of the standard Gibbs free energy change (G) in chemical reactions?
The standard Gibbs free energy change (G) in chemical reactions indicates whether a reaction is spontaneous (G 0) or non-spontaneous (G 0). It helps determine the direction and feasibility of a reaction under standard conditions.
Is the change in entropy, delta S, positive or negative for a spontaneous reaction?
For a spontaneous reaction, the change in entropy (delta S) is typically positive.
What is true about the numerical value of the Gibbs free-energy change for a spontaneous reaction?
For a spontaneous reaction, the numerical value of the Gibbs free-energy change (ΔG) is negative, indicating that the reaction is energetically favorable and will proceed in the forward direction. This negative ΔG means that the system is releasing energy and increasing in entropy during the reaction.
Does clausious inequality satisfy only for spontaneous process?
Clausius inequality is a fundamental principle in thermodynamics that applies to all thermodynamic processes, not just spontaneous ones. It states that for any reversible process, the change in entropy (ΔS) is equal to the heat transfer (Q) divided by the temperature (T), while for irreversible processes, ΔS is greater than Q/T. Therefore, it provides a criterion for the direction of spontaneous processes but is applicable to both spontaneous and non-spontaneous processes.
What kind of reaction tends to be spontaneous?
Reactions that are exothermic
What kind of reaction occurs when the entropy change of an endothermic reaction is negative?
The reaction is exothermic
How can one determine if a process is spontaneous?
A process is spontaneous if it occurs without any external influence or assistance. One way to determine if a process is spontaneous is by calculating the change in Gibbs free energy (G). If G is negative, the process is spontaneous.
Why the spontaneous radiation incoherent?
Spontaneous radiation is incoherent because it occurs randomly with no fixed phase relationship between emitted photons. This randomness results in a broad range of frequencies and directions for the emitted radiation, making it incoherent.
Is the reaction spontaneous or non-spontaneous at 298 k?
To determine if a reaction is spontaneous or non-spontaneous at 298 K, we can use the Gibbs free energy equation, ΔG = ΔH - TΔS. If ΔG is negative, the reaction is spontaneous; if ΔG is positive, it is non-spontaneous. The values of ΔH (enthalpy change) and ΔS (entropy change) must be known to evaluate the spontaneity at this temperature. Without specific values for ΔH and ΔS, we cannot definitively conclude the spontaneity.
What form a spontaneous reaction at 298 K?
A spontaneous reaction at 298 K is one in which the Gibbs free energy change (ΔG) is negative. This means that the reaction is energetically favorable and will proceed in the forward direction without the need for external energy input.
When is a red-ox reaction spontaneous?
A redox reaction is spontaneous when the overall change in Gibbs free energy (ΔG) is negative. This typically occurs when the standard electrode potentials of the half-reactions involved indicate a favorable direction for electron flow, resulting in a positive cell potential (E°). In simpler terms, a spontaneous redox reaction can occur without external energy input, driven by the inherent chemical properties of the reactants.
