Electron affinity of an element is defined as the energy released by adding an electron to a gaseous atom of the element. With the electronic configuration of the fluroine atom being [Ne] 2s2 2p5, it needs just one more electron to form the fluoride ion (F-) which has the noble gas structure and is much more stable.
Yes. It's true. Chlorine has the highest electron affinity, then Fluorine, Bromine and Iodine
Fluorine has greater electron affinity than bromine, or any other element.
Generally electron affinity goes up as you go from left to right across the periodic table, and decreases as you go down a column. However, fluorine is an exception -- and the element with the highest electron affinity is chlorine.(Note that the most electronegative element is fluorine however; 'electronegativity' is not exactly the same as 'electron affinity'.)Electronegativity is the ability of an atom in a molecule to draw bonding electrons to itselfElectron affinity is a measure of the energy change when an electron is added to a neutral atom to form a negative ion.The reason that the electron affinity is not as high as might otherwise be predicted for fluorine, is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).
Fluorine has a lower electron affinity than oxygen. This is because fluorine already has a full outer shell of electrons and adding another electron would create repulsion due to electron-electron interactions. Oxygen, on the other hand, has space in its outer shell to accept an additional electron more easily.
Generally electron affinity goes up as you go from left to right across the Periodic Table, and decreases as you go down a column. However, fluorine is an exception -- and the element with the highest electron affinity is chlorine (note that the most electronegative element is fluorine however).The reason that the electron affinity is not as high as might otherwise be predicted for fluorine is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).Note that there are a number of other exceptions to the general rule of electron affinity increasing towards the upper right corner -- see the Related Questions links to the left for an explanation of some of those other exceptions.See also the Web Links to the left for more information about electron affinities and the fluorine-chlorine exception.
Yes. It's true. Chlorine has the highest electron affinity, then Fluorine, Bromine and Iodine
Fluorine has higher electron affinity than any other element.
Fluorine has greater electron affinity than bromine, or any other element.
The halogen with the least-negative electron affinity is astatine. Electron affinity and electronegativities decreases down a group. Since astatine is the last halogen located in Group 17 as you move down the column from fluorine, it has the least negative electron affinity.
Fluorine has the highest electron affinity because it has a small atomic size and high effective nuclear charge, which results in a strong attraction between the nucleus and incoming electrons. This strong attraction allows fluorine to readily accept an additional electron and achieve a stable electron configuration.
Generally electron affinity goes up as you go from left to right across the periodic table, and decreases as you go down a column. However, fluorine is an exception -- and the element with the highest electron affinity is chlorine.(Note that the most electronegative element is fluorine however; 'electronegativity' is not exactly the same as 'electron affinity'.)Electronegativity is the ability of an atom in a molecule to draw bonding electrons to itselfElectron affinity is a measure of the energy change when an electron is added to a neutral atom to form a negative ion.The reason that the electron affinity is not as high as might otherwise be predicted for fluorine, is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).
Fluorine has a lower electron affinity than oxygen. This is because fluorine already has a full outer shell of electrons and adding another electron would create repulsion due to electron-electron interactions. Oxygen, on the other hand, has space in its outer shell to accept an additional electron more easily.
No, it is not. Electron affinity follows a trend like electronegativity and hence increases as we move from left to right across a period. So, Fluorine has the highest electron affinity among 1st period elements.
Generally electron affinity goes up as you go from left to right across the Periodic Table, and decreases as you go down a column. However, fluorine is an exception -- and the element with the highest electron affinity is chlorine (note that the most electronegative element is fluorine however).The reason that the electron affinity is not as high as might otherwise be predicted for fluorine is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).Note that there are a number of other exceptions to the general rule of electron affinity increasing towards the upper right corner -- see the Related Questions links to the left for an explanation of some of those other exceptions.See also the Web Links to the left for more information about electron affinities and the fluorine-chlorine exception.
AnswerElectron affinity is the energy released when we add an electron to the outermost orbit of the atom. Halogens are the higher in electron affinity, and chlorine has the higher electron affinity than rest of the halogens. The irregularity in the electron affinity trend between Cl and F is due to the small size of the F atom. Although F definitely has a higher attraction for an electron than Cl (as evidenced by its high electro negativity value), the small size of the F atom means that adding an electron creates significant repulsion. Since electron affinity is an energy measurement, the total energy associated with electron affinity winds up being the energy that is released by the electron binding to the nucleus, minus the energy involved in overcoming the electrical repulsion in the outer shell.This makes the fluoride anion so formed unstable due to a very high charge/mass ratio. Also, fluorine has no d electrons which limits its atomic size. As a result, fluorine has an electron affinity less than that of chlorine.
Electron affinity is the energy released when an atom gains an electron to form a negative ion, while electron gain enthalpy is the enthalpy change accompanying the addition of an electron to a gaseous atom. Electron affinity is a specific term used in the context of forming an ion, while electron gain enthalpy is a general term for the enthalpy change associated with gaining an electron.
No, sulfur has a higher electron affinity than oxygen. Electron affinity is the energy released when an atom gains an electron to form a negative ion, and sulfur's larger size and higher effective nuclear charge make it more likely to attract an additional electron compared to oxygen.