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By heating the nut (and avoiding the bolt as much as possible) the metal expands, this increases the size of the hole in the middle, releasing pressure against the bolt and allowing you to turn the nut while hot. Wear heat proof gloves, eye protection and have extinguishing equipment and cold water to hand. The level of heat required is often described as "cherry red" and can cause some types of metal to permanently change their hardness... be very careful if you are working on safety critical things like brakes, replace all affected parts.

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Q: Why is heat used to loosen a rusted nut on a bolt?
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