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Rust is associated with degradation of iron-based tools and structures. As rust has a much higher volume than the originating mass of iron, its build-up can also cause failure by forcing apart adjacent parts - a phenomenon sometimes known as "rust smacking". It was the cause of the collapse of the Mianus river bridge in 1983, when the bearings rusted internally and pushed one corner of the road slab off its support. Rust was also an important factor in the Silver Bridge disaster of 1967 in West Virginia, when a steel suspension bridge collapsed in less than a minute, killing 46 drivers and passengers on the bridge at the time.

Kinzua Bridge in Pennsylvania was blown down by a tornado in 2003 largely because the central base bolts holding the structure to the ground had rusted away, leaving the bridge resting by gravity alone.

Similarly, corrosion of concrete-covered steel and iron can cause the concrete to spall, creating severe structural problems. It is one of the most common failure modes of reinforced concrete bridges.

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