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Defrost uses the a/c, if it doesn't smell the same with a/c only on. The smell is coming from the blower motor. BMW's for example have a problem where the blower blade contacts the plastic housing and causes it to rub/melt.

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Q: Why would your car defroster smell like burning rubber?
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What would smell like burning rubber in a 1995 dodge neon?

The burning rubber smell in the tranmisson breaking apart inside.


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