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although you are proabably cooking it to the full safe temperature zone, i would not recommend using it in your soup after being left out overnight, it contains meat and unless you would normally eat meat that has been left out over night it probably isn't a good idea.

A diffferent answer:

Ham, by definition, is cured meat, and as such is less vulnerable to spoilage than uncured meats. To be safe, though, a ham hock left unrefrigerated overnight should be thoroughly cooked before eaten.

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