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A Silver mirror does not appear as ketones cannot be further oxidized unlike aldehydes in which a silver mirror does appear.

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What is the mechanism of the Tollens test and how does it differentiate between aldehydes and ketones?

The Tollens test involves the oxidation of aldehydes to carboxylic acids by silver ions in a basic solution. This forms a silver mirror on the inside of the test tube. Ketones do not react with Tollens reagent and do not produce a silver mirror. This test is used to differentiate between aldehydes and ketones based on their reactivity with Tollens reagent.


What is the principles of tollen's test?

The principle of Tollens' test is to distinguish between aldehydes and ketones. It involves the reduction of silver ions to silver metal in the presence of aldehydes, which results in the formation of a silver mirror on the inner surface of the test tube. Ketones do not give a positive Tollens' test because they do not undergo this reaction with silver ions.


Why Tollens reagent does not react with ketone?

Tollens reagent is a mild oxidizing agent that reacts with aldehydes to produce a silver mirror. Ketones, however, do not have a hydrogen atom bonded to the carbonyl group, making them resistant to oxidation by Tollens reagent. As a result, ketones do not react with Tollens reagent.


What substances give a positive tollens test?

When adding the aldehyde or ketone to Tollens' reagent, the test tube is put in a warm water bath. If the reactant under test is an aldehyde, Tollens' test results in a silver mirror. If the reactant is a ketone, it will not react because a ketone cannot be oxidized easily. A ketone has no available hydrogen atom on the carbonyl carbon that can be oxidized - unlike an aldehyde, which has this hydrogen atom.


What test is used to show the reducing property of an aldehyde and a ketone?

The Tollens' test is commonly used to show the reducing property of an aldehyde. In this test, an aldehyde will reduce silver ions in Tollens' reagent to form a silver mirror. Ketones do not show this reaction.


what is the outcome of tollens reagent reacting with methanal, ethanol and propanone?

The outcome of the Tollens reagent reacting with methanal (formaldehyde), ethanol (ethyl alcohol), and propanone (acetone) is the formation of metallic silver (Ag) in the case of methanal, while ethanol and propanone do not show a significant reaction with Tollens reagent. Tollens reagent is used as a chemical test to distinguish between aldehydes and ketones, where aldehydes react to produce a silver mirror, while ketones do not react.


Does the tollens test deal with alkenes?

No, the Tollen's Silver Mirror Test only confirms the presence of aldehydes.


Why ketone do not react with Fehlings solution and Tollens reagent?

Ketones do not react with Fehling's solution or Tollens' reagent because they lack the free aldehyde group necessary for these reactions to occur. Both Fehling's solution and Tollens' reagent depend on the presence of the aldehyde group to participate in redox reactions that lead to the formation of a colored precipitate. Without this aldehyde group, ketones do not undergo these reactions.


Why fructose gives positive tollen reagent test?

Only aldehydes give a positive Tollens test. However, under the strongly basic conditions of the test, alpha-hydroxy ketones can isomerize to aldehydes, so they will also give a positive Tollens test. Fructose is an alpha-hydroxy ketone.


Why pyrrole-2-aldehyde does not respond to tollens reagent?

Pyrrole-2-aldehyde does not respond to Tollens reagent because it is not a reducing sugar. Tollens reagent (silver nitrate) is used to test for the presence of aldehyde groups, which are commonly found in reducing sugars. Reducing sugars contain aldehyde groups and are capable of donating electrons to Tollens reagent, forming a silver mirror on the test tube wall. Pyrrole-2-aldehyde does not contain aldehyde groups, and therefore is not a reducing sugar. As a result, it does not react with Tollens reagent.


How Methanal reacts with tollens reagant?

Methanal (formaldehyde) reacts with Tollens' reagent, which contains silver ions in an alkaline solution, to produce silver metal. During this reaction, methanal is oxidized to formic acid, while the silver ions are reduced to metallic silver, resulting in a characteristic silver mirror on the inner surface of the reaction vessel. This reaction is a classic test for aldehydes, as they can reduce Tollens' reagent, unlike most ketones.


What is the class of compound when no precipitates formed with fehling and tollens reagent?

The compound is likely a ketone. Ketones do not react with Fehling's or Tollens' reagent to form precipitates, unlike aldehydes which would undergo redox reactions resulting in a visible change.