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Standardization of sodium thiosulfate uses potassium iodate with excess potassium iodide and acidified. Iodine is liberated and that is titrated with sodium thiosulfate.

KIO3 + 5KI + 3H2SO4 -----> 3K2SO4 + 3H2O + 3 I2

I2 + 2Na2S2O3 -------> 2NaI + Na2S4O6

So 1 mole of KIO3 produces 3 moles of Iodine. 1 moles of iodine reacts with 2 moles of thiosulfate. So 6 moles of sodium thiosulfate react with 1 mole of potassium iodate KIO3.

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