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The substance with the lowest known melting temperature is the noble gas helium.

Helium will not freeze at atmospheric pressures, but will freeze at about 1K (-272oC) when pressure is increased to 2.5 MPa (about 25 times atmospheric pressure).

Due to helium's small Atomic Mass, and relative insucceptibility to dispersion forces, it is unlikely that there is a substance with a lower melting temperature.

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